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dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)

dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)

CAS: 203714-71-0

Molecular Formula: C28H45Cl2OPRu

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dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1) - Names and Identifiers

Name dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)
Synonyms Hoveyda-Grubbs Catalyst 1st Generation
HOVEYDA-GRUBBS CATALYST 1ST GENERATION
DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)(TRICYCLOHEXYLPHOSPHINE)RUTHENIUM(II)
Dichloro(O-Isopropoxyphenylmethylene)(Tricyclohexylphosphine)Ruthenium(Ii)
Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II)
Dichloro[[2-(1-methylethoxy-O)phenyl]methylene](tricyclohexylphosphine)ruthenium
RUTHENIUM, DICHLORO[[2-(1-METHYLETHOXY)PHENYL]METHYLENE](TRICYCLOHEXYLPHOSPHINE)
RutheniuM,dichloro[[2-(1-Methylethoxy-kO)phenyl]Methylene-kC](tricyclohexylphosphine)-,(SP-5-41)-
Hoveyda-Grubbs Catalyst 1st Generation,Dichloro(o-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium(II)
CAS 203714-71-0
EINECS 692-988-0
InChI InChI=1/C18H33P.C10H12O.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)11-10-7-5-4-6-9(10)3;;;/h16-18H,1-15H2;3-8H,1-2H3;2*1H;/q;;;;+2/p-2/rC18H33P.C10H12Cl2ORu/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8(2)13-10-6-4-3-5-9(10)7-14(11)12/h16-18H,1-15H2;3-8H,1-2H3
InChIKey KMKCJXPECJFQPQ-UHFFFAOYSA-L

dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1) - Physico-chemical Properties

Molecular FormulaC28H45Cl2OPRu
Molar Mass600.61
Melting Point195-197°C(lit.)
Boling Point383.4°C at 760 mmHg
Flash Point195.6°C
Vapor Presure9.7E-06mmHg at 25°C
Storage Condition2-8°C

dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1) - Risk and Safety

Hazard SymbolsF - Flammable
Flammable
Risk Codes11 - Highly Flammable
UN IDsUN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany3

dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1) - Introduction

dichloro{[2-(1-methylethoxy)phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is an organic compound with the chemical formula [LICLIZOTH (CCHI) OCH?) C (H? CH? P(C? H)] Ru. The following is a detailed description of the properties, uses, preparation and safety information of the compound:

Nature:
-Appearance: Colorless to light yellow solid
-Density: 1.31g/cm³
-Melting point: 130-132 ° C
-Solubility: Soluble in organic solvents such as dimethylformamide and dichloromethane

Use:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is a hydrogenation catalyst, which is often used to catalyze the hydrogenation of olefins in organic synthesis.
-It can also be used as a homogeneous catalyst to play a catalytic role in reactions such as the Heterocyclic Synthesis of alkenes and indole.
-In addition, it can also catalyze the manganese carbonyl reduction reaction and benzene ring carbonylation reaction of alkynes.

Method:
dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) it is possible to combine RuCl3 · 3H ₂ O and [cl₂ (c≡halready (CH) och₂) in methylene chloride. The C (C (H)) reaction is obtained.

Safety Information:
- dichloro{[2-(1-methyllethoxy) phenyl] methyllidene} ruthenium-tricyclohexylphosphane (1:1) is stable at room temperature, but contact with strong oxidants should be avoided.
-It is an organic catalyst and should be avoided by inhalation or skin contact. Wear appropriate protective equipment such as gloves and eye protection during operation.
-In case of contact, flush the affected area immediately with plenty of water and seek medical help.
-When storing and using, please follow the safety procedures and chemical storage requirements.
Last Update:2024-04-10 22:29:15
dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)
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View History
dichloro{[2-(1-methylethoxy)phenyl]methylidene}ruthenium - tricyclohexylphosphane (1:1)
非那卡因
甘磷酸胆碱,甘油磷脂酰胆碱
苄氧基溴,苯甲酰溴
溴化环己羰基
DIBRIMO(1,5-CYCLOOCTADIENE)PLATINUM(II)
去甲基托品醇(NORTROPINE)
舒必利杂质G (EP)
2-[(METHYLSULFANYL)METHYL]PYRIDINE
环戊酮-2-甲酸甲酯
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